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Notes -
To me a digestif is usually pretty herbal; ie. Benedictine, Jaeger, something like that.
So maybe the bitterness or non-alcohol components could have some effect?
Drinking something like grappa after dinner (or coffee drinks) is just a way of shaking off the torpor so you can party on -- which I suppose is probably better for digestion than lying on the couch for an hour, but more like a side effect.
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