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I think that you are oversimplifying things. The utility of chemical weapons depends a lot specific conditions. For example, they were used a lot on the Western Front in WW1 (though they did not lead to a military breakthrough), while they saw little to no combat use in WW2, not because Hitler was a nice guy who would never stoop so low, but because his blitzkrieg tactics did not require area denial.
So CW depend on doctrine, and doctrine is not something which you can just pick. The Reichswehr could not simply have invented the blitzkrieg, they lacked the vehicles to pull that off. The US military is very long on equipment and rather short on atrocities. They are highly mechanized (which means that CW for area denial are less useful to them), but any war they join is likely to be a voluntary overseas engagement, and they have an electorate back home which tends to get upset over atrocities. For Assad and his ilk, the calculation is different. He did not have the mobility to do blitzkrieg, but he also did not have to consider what his electorate could stomach.
If you are not trying to achieve a tactical objective, but the goal is to spread terror, then chemical weapons are probably 10x as effective per death than bombs are, and radiological weapons might be 100x as effective as plain old explosives. That Japanese cult could have achieved the same death toll of their infamous Sarin attack by throwing a few pipe bombs into a crowded subway car at a fraction of the operational complexity of synthesizing a nerve agent. But if they had done that, their attack might not even have made the top spot in international news, and would long have been forgotten outside Japan.
Chemical weapons are ineffective against actual militaries, the Reichswehr spent the latter half of the great war figuring that out. They're effective against mobs of unarmed protestors, which is who Assad actually gassed- but they're less effective than munitions(which Assad did not have enough of, he was filling barrels with oil and lighting fuses before pushing them out of helicopters). They're not great for targeting villagers, but Saddam didn't run a militarily optimal regime. People who can afford better(chemical weapons are cheap), do.
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It's the same as dirty bombs. The radioactivity from a dirty bomb will not, realistically, cause particularly many cancer cases. It will, however, cause an absolutely absurd amount of panic, and I mean that both in the literal sense and as an intensifier.
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