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I am NOT soliciting information on how to procure illicit substances... but I am idly curious how rationalists are getting precisely dosed psychedelics

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The safest way is to stick to well researched legal psychedelics. Legal supply chains are generally more reliable than black market supply chains. The specific psychedelic legality varies depending on your location so there is no general answer. In the US you can join one of the legal psychedelic religions and get reliable access you hallucinogens. In Oregon and Colorado many commonly illegal psychedelics are now legal. You could also order mushroom spores and grow your own. Failing any of that you can go to the darknets and do direct testing yourself or send away testing.