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I am NOT soliciting information on how to procure illicit substances... but I am idly curious how rationalists are getting precisely dosed psychedelics

Safety being both a major problem with illicit drugs and a major concern of rationalists, this raised an eyebrow. The simplest explanation is that the people concerned with safety aren't the people using psychedelics and that I underestimated the availability of psychedelics through whatever the normal drug-buying channels are (and perhaps self-experimenters overstate the precision of the doses?), but I'm curious about other possible explanations. Assuming commonality, which I do not take for granted, the two most plausible explanations I came up with were:

Is there a rationalist Bear (preferred name of Augustus Owsley Stanley III, another early psychedelicist who started weird and became extremely weird) out there? As I understand it, synthesizing LSD requires serious know-how and equipment, but there are surely rationalist synthetic chemists and perhaps one is willing and capable.

Dark-web sales and purity testing labs? That meshes with the techno-libertarian side of things, but I have no idea how those labs operate and I'm guessing buying drugs online practically requires you to commit a federal crime in the US, which is a pretty big hazard.

I'm guessing the simplest explanation is the correct one, to the extent that there's a connection between rationalists and psychedelics, in the first place, but if someone actually knows, I'd rather know than guess.

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Not that I have an issue with it but is that clearnet site even legal in Canada? Per https://www.canada.ca/en/health-canada/services/substance-use/controlled-illegal-drugs/magic-mushrooms.html

The production, sale and possession of magic mushrooms are illegal in Canada. There is increasing interest in the potential therapeutic uses of magic mushrooms and of psilocybin, one of the active ingredients in magic mushrooms. While clinical trials with psilocybin have shown promising results, at this time, there are no approved therapeutic products containing psilocybin in Canada or elsewhere. Clinical trials are the most appropriate and effective way to advance research with unapproved drugs such as psilocybin while protecting the health and safety of patients.

No, but it's seen as not worth the effort to police. They're only really worried about kids getting sent mushrooms.