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I am NOT soliciting information on how to procure illicit substances... but I am idly curious how rationalists are getting precisely dosed psychedelics

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If you're in canada, you can just order shrooms online, though you'll have to pay by interac transfer bank-to-bank. They will arrive, and they will be real and effective. If you want to precisely dose shrooms, blend them into very small bits, then use a milligram scale to measure and make a shroom tea. That's how I do it anyway. For other psychedelics, another good source is https://my.indiamart.com/, though if you search directly on the website you won't find them, you need to go on google, and do a specific site search like "site: indiamart.com ketamine", and you'll find this close to the top links, which is just straight up a vial of ketamine. I've bought lots of stuff from indiamark, including blood pressure medications, a long-term supply of antibiotics for my disaster prep bag, semaglutide, modafinil, etc. and they've all made it past the canadian border safe and sound, and were completely effective as far as I can see, though I didn't test them in a lab.

To minimize legal risk you can also get stuff like 1P-LSD, which is different enough from LSD as to be in a legal gray area, but still a pretty potent psychedelic.

Not that I have an issue with it but is that clearnet site even legal in Canada? Per https://www.canada.ca/en/health-canada/services/substance-use/controlled-illegal-drugs/magic-mushrooms.html

The production, sale and possession of magic mushrooms are illegal in Canada. There is increasing interest in the potential therapeutic uses of magic mushrooms and of psilocybin, one of the active ingredients in magic mushrooms. While clinical trials with psilocybin have shown promising results, at this time, there are no approved therapeutic products containing psilocybin in Canada or elsewhere. Clinical trials are the most appropriate and effective way to advance research with unapproved drugs such as psilocybin while protecting the health and safety of patients.

No, but it's seen as not worth the effort to police. They're only really worried about kids getting sent mushrooms.